منابع مشابه
Cooperative bimetallic oxidative addition reactions*
The factors that control the oxidation of metals in bimetallic complexes are investigated in relation to the possibility of developing one-site addition two-metal oxidation reactions such as those that occur in the respiratory protein, hemerythrin. It is shown that the behavior of bimetallic complexes is not represented by the sum of the analogous monometallic parts because of metal and ligand ...
متن کاملEnantioselective oxidative boron Heck reactions.
This review highlights the use of the oxidative boron Heck reaction in enantioselective Heck-type couplings. The enantioselective oxidative boron Heck reaction overcomes several limitations of the traditional Pd(0)-catalysed Heck coupling and has subsequently allowed for intermolecular couplings of challenging systems such as cyclic enones, acyclic alkenes, and even site selectively on remote a...
متن کاملOxidative and Reductive Enzymes: Phase I Reactions
Both metabolism and excretion can be viewed as processes responsible for elimination of drug (parent and metabolite) from the body. Drug metabolism changes the chemical structure of a drug to produce a drug metabolite, which is frequently but not universally less pharmacologically active. Metabolism also renders the drug compound more water soluble and therefore more easily excreted. Drug metab...
متن کاملOxidation-reduction reactions of metal ions.
Several metal or metalloid ions exist in multiple oxidation states and can undergo electron transfer reactions that are important in biological and environmental systems. There are endogenous metal ions such as iron, copper, and cobalt that participate in oxidation-reduction reactions with species of oxygen like molecular dioxygen, superoxide, and hydrogen peroxide. These reactions may be modul...
متن کاملOxidation reactions by prostaglandin cyclooxygenase-hydroperoxidase.
oxidations of organic sulfides, amines, and even enzymes catalyzed by purified and microsomal forms of prostaglandin cyclooxygenase-hydroperoxidase have been studied using O2 incorporation into arachidonic acid to monitor oxygenase and [14C]15-hydroperoxyprostaglandin E2 reduction to prostaglandin E2 to measure hydroperoxidase. The oxygenase was protected by phenol against the irreversible deac...
متن کاملذخیره در منابع من
با ذخیره ی این منبع در منابع من، دسترسی به آن را برای استفاده های بعدی آسان تر کنید
ژورنال
عنوان ژورنال: Organic Process Research & Development
سال: 2015
ISSN: 1083-6160,1520-586X
DOI: 10.1021/acs.oprd.5b00341